Sulfonic acid functionalized cellulose-derived (nano)materials: Synthesis and application.

The preparation/application of heterogeneous (nano)materials from natural resources has currently become increasingly fascinating for researchers. Cellulose is the most abundant renewable polysaccharide on earth. The unique physicochemical, structural, biological, and environmental properties of this natural biopolymer have led to its increased application in many fields. The more desirable features of cellulose-based (nano)materials such as biodegradability, renewability, biocompatibility, cost-effectiveness, simplicity of preparation, environmentally friendly nature, and widespread range of applications have converted them into promising compounds in medicine, catalysis, biofuel cells, and water/wastewater treatment processes. Functionalized cellulose-based (nano)materials containing sulfonic acid groups may prove to be one of the most promising sustainable bio(nano)materials of modern times in the field of cellulose science and (nano)technology owing to their intrinsic features, high crystallinity, high specific surface area, abundance, reactivity, and recyclability. In this review, the developments in the application of sulfonated cellulose-based (nano)materials containing sulfonic acid (-SO3H) groups in catalysis, water purification, biological/biomedical, environmental, and fuel cell applications have been reported. This review provides an overview of the methods used to chemically modify cellulose and/or cellulose derivatives in different forms, including nanocrystals, hydrogels, films/membranes, and (nano)composites/blends by introducing sulfonate groups on the cellulose backbone, focusing on diverse sulfonating agents utilized and substitution regioselectivity, and highlights their potential applications in different industries for the generation of alternative energies and products.

Experimental characterization and finite element investigation of SiO2 nanoparticles reinforced dental resin composite.

In this study, a commercial dental resin was reinforced by SiO2 nanoparticles (NPs) with different concentrations to enhance its mechanical functionality. The material characterization and finite element analysis (FEA) have been performed to evaluate the mechanical properties. Wedge indentation and 3-point bending tests were conducted to assess the mechanical behavior of the prepared nanocomposites. The results revealed that the optimal content of NPs was achieved at 1% SiO2, resulting in a 35% increase in the indentation reaction force. Therefore, the sample containing 1% SiO2 NPs was considered for further tests. The morphology of selected sample was examined using field emission scanning electron microscopy (FE-SEM), revealing the homogeneous dispersion of SiO2 NPs with minimal agglomeration. X-ray diffraction (XRD) was employed to investigate the crystalline structure of the selected sample, indicating no change in the dental resin state upon adding SiO2 NPs. In the second part of the study, a novel approach called iterative FEA, supported by the experiment wedge indentation test, was used to determine the mechanical properties of the 1% SiO2-dental resin. Subsequently, the accurately determined material properties were assigned to a dental crown model to virtually investigate its behavior under oblique loading. The virtual test results demonstrated that most microcracks initiated from the top of the crown and extended through its thickness.

Sandwich-type double-layer piezoelectric nanogenerators based on one- and two-dimensional ZnO nanostructures with improved output performance.

Piezoelectric nanogenerators (PENGs) have attracted great interest owing to their broad range application in environmental mechanical energy harvesting to power small electronic devices. In this study, novel flexible and high-performance double-layer sandwich-type PENGs based on one-dimensional (1-D) and two-dimensional (2-D) zinc oxide (ZnO) nanostructures and Ni foam as the middle layer have been developed. The morphology and structure of 1- and 2-D ZnO nanostructures have been studied by scanning electron microscopy (SEM) and X-ray diffraction (XRD). To investigate the effect of structural design on the piezoelectric performance, single-layer PENGs were also fabricated. The piezoelectric output of all prepared PENGs were evaluated under different human impacts at various forces and frequencies. The double-layer designed PENGs showed a two times larger voltage output compared to the single-layer PENGs, and the use of Ni foam as middle-layer and of 2-D ZnO nanosheets (compared to 1-D nanorods) was also found to increase the performance of the designed PENGs. The working mechanism of the prepared PENGs is also discussed. The design of nanogenerators as double-layer sandwich structures instead of two integrated single-layer devices reduces the overall preparation time and processing steps and enhances their output performance, thus opening the gate for widening their practical applications.

Correction to "Upgraded Valorization of Biowaste: Laser-Assisted Synthesis of Pd/Calcium Lignosulfonate Nanocomposite for Hydrogen Storage and Environmental Remediation".

[This corrects the article DOI: 10.1021/acsomega.9b04149.].

Sensing Properties of g-C3N4/Au Nanocomposite for Organic Vapor Detection.

Alleviating the increasingly critical environmental pollution problems entails the sensing of volatile organic compounds (VOCs) as a hazardous factor for human health wherein the development of gas sensor platforms offers an efficient strategy to detect such noxious gases. Nanomaterials, particularly carbon-based nanocomposites, are desired sensing compounds for gas detection owing to their unique properties, namely a facile and affordable synthesis process, high surface area, great selectivity, and possibility of working at room temperature. To achieve that objective, g-C3N4 (graphitic carbon nitride) was prepared from urea deploying simple heating. The ensuing porous nanosheets of g-C3N4 were utilized as a substrate for loading Au nanoparticles, which were synthesized by the laser ablation method. g-C3N4 presented a sensing sensitivity toward organic vapors, namely methanol, ethanol, and acetone vapor gases, which were significantly augmented in the presence of Au nanoparticles. Specifically, the as-prepared nanocomposite performed well with regard to the sensing of methanol vapor gas and offers a unique strategy and highly promising sensing compound for electronic and electrochemical applications.

Synthesis of bentonite/Ag nanocomposite by laser ablation in air and its application in remediation.

In this research, a simple, green, and efficient approach is described to produce novel bentonite/Ag nanocomposite wherein the preparation of Ag nanoparticles (Ag NPs) deployed the laser ablation method in air; Ag NPs are deposited on the bentonite via the magnetic stirring method. The structural and morphological characterization of the as-prepared bentonite/Ag nanocomposite (denoted as B/Ag30, 30 min being the laser ablation time) is accomplished using different methods. Additionally, the catalytic assessment of the ensued composite exhibited excellent catalytic reduction/degradation activity for common aqueous pollutants namely methyl orange (MO), congo red (CR) and 4-nitrophenol (4-NP) utilizing NaBH4 as reductant. Furthermore, the recycling tests displayed the high stability/reusability of B/Ag30 nanocomposite for at least 4 runs with retention of catalytic prowess.

Preparation of Polycarbonate-ZnO Nanocomposite Films: Surface Investigation after UV Irradiation.

Polycarbonate (PC)-ZnO films with different percentages of ZnO were prepared by a solution stirring technique and subjected to ultraviolet (UV; λ = 254 nm) irradiation. Structural parameters of the samples and the effects of UV irradiation on the surface properties of the PC and PC-ZnO nanocomposites were evaluated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), water contact angle (WCA) measurements, and a Vickers microhardness (HV) tester. The XRD patterns of the nanocomposite films were found to show an increase in crystallinity with the increasing ZnO nanoparticles percentage. The WCA was found to be reduced from 90° to 17° after 15 h of UV irradiation, which could be ascribed to the oxidation of the surface of the samples during the irradiation and exposure of the ZnO nanoparticles, a result that is also supported by the obtained XPS data. The microhardness value of the PC-ZnO films including 30 wt.% ZnO enhanced considerably after UV radiation, which can also be attributed to the exposition of the ZnO nanoparticles after photodegradation of the PC superficial layer of the nanocomposite films.

Hybrid superhydrophobic/hydrophilic patterns deposited on glass by laser-induced forward transfer method for efficient water harvesting.

In recent years, the combination of factors such as growing population and global climate change has resulted in freshwater shortages. Therefore, water harvesting from the atmospheric fog in order to produce freshwater supply inspired by nature has received much attention. The water harvesting capability of the creatures is significantly based on the combination of both wettability states on their surfaces. In this study, a facile physicochemical hybrid method was used for the fabrication of glass surfaces with contrast wettability. First, fractal and regular repeated geometric patterns were deposited on a glass substrate using brass sheet as donor material by laser induced forward transfer (LIFT) method. Subsequently, stearic acid (SA) treatment was used to convert the wettability of the superhydrophilic (SHL) deposited patterns on glass to superhydrophobic. In order to investigate the effect of the shape of designed patterns on glass surfaces in the water harvesting efficiency, the amount of collected water for a period of time from untreated hydrophilic (HL) glass, superhydrophobic (SHB) glass and hybrid superhydrophobic/hydrophilic (SHB-HL) surfaces were measured. The obtained results indicate that the hybrid of superhydrophobic and hydrophilic regions and selecting the optimal pattern can improve the water harvesting performance by up to 300%.

Biowaste- and nature-derived (nano)materials: Biosynthesis, stability and environmental applications.

Due to the environmental pollution issues and the supply of drinking/clean water, removal of both inorganic and organic (particularly dyes, nitroarenes, and heavy metals) to non-dangerous products and useful compounds are very important transformations. The deployment of sustainable and eco-friendly nanomaterials with exceptional structural and unique features such as high efficiency and stability/recyclability, high surface/volume ratio, low-cost production routes has become a priority; nonetheless, numerous significant challenges/restrictions still remained unresolved. The immobilization of green synthesized metal nanoparticles (NPs) on the natural materials and biowaste generated templates have been analyzed widely as a greener approach due to their environmentally friendly preparation methods, earth-abundance, cost-effectiveness with low energy consumption, biocompatibility, as well as adjustability in various cases of biomolecules as bioreducing agents. Natural and biowaste materials are widely considered as important sources to fabricate greener and biosynthesized types of metal, metal oxide, and metal sulfide nanomaterials using plant extracts. Integrating green synthesized nanoparticles with various biotemplates offers new practical composites for mitigating environmental challenges. In this review, degradation of dyes, reduction of toxic nitrophenols, absorption of heavy metals, and other hazardous/toxic environmental pollutants from contaminated water bodies using biowaste- and nature-derived nanomaterials are highlighted.

Biopolymer-derived (nano)catalysts for hydrogen evolution via hydrolysis of hydrides and electrochemical and photocatalytic techniques: A review.

Over the course of a few decades, the concern of environmental damages of fossil fuels, an increase in CO2 emission and a decrease of hydrogen have been growing more and more. Accordingly, hydrogen production is a crucial issue nowadays. Different polymers are applied to attain the purpose. Among all polymers, biodegradables polymers are the best choices to develop the main aim. Polysaccharides and proteins are biodegradable polymers with unique places and advantages with regards to their ecofriendly properties. There are different techniques to apply and achieve the foremost purpose. It is worthwhile to mention that green and facile methods are always attracting attention in different aspects and fields. The three non-polluting and economical techniques, that is, electrochemical hydrogen evolution reaction (HER), photocatalytic technique, and hydrolysis of hydrides, are reviewed in this paper. This review helps researchers, who are environment supporters, to evaluate and choose the most ecological biopolymers and processes in their work.

Large Optical Nonlinearity of the Activated Carbon Nanoparticles Prepared by Laser Ablation.

Carbon nanoparticles (CNPs) with high porosity and great optical features can be used as a luminescent material. One year later, the same group investigated the NLO properties CNPs and boron-doped CNPs by 532 nm and 1064 nm laser excitations to uncover the underlying physical mechanisms in their NLO response. Hence, a facile approach, laser ablation technique, was employed for carbon nanoparticles (CNPs) synthesis from suspended activated carbon (AC). Morphological properties of the prepared CNPs were studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). UV-Vis and fluorescence (FL) spectra were used to optical properties investigation of CNPs. The size distribution of nanoparticles was evaluated using dynamic light scattering (DLS). The nonlinear optical (NLO) coefficients of the synthesized CNPs were determined by the Z-scan method. As a result, strong reverse saturable absorption and self-defocusing effects were observed at the excitation wavelength of 442 nm laser irradiation. These effects were ascribed to the presence of delocalized π-electrons in AC CNPs. To the best of our knowledge, this is the first study investigating the NLO properties of the AC CNPs.

Lignin, lipid, protein, hyaluronic acid, starch, cellulose, gum, pectin, alginate and chitosan-based nanomaterials for cancer nanotherapy: Challenges and opportunities.

Although nanotechnology-driven drug delivery systems are relatively new, they are rapidly evolving since the nanomaterials are deployed as effective means of diagnosis and delivery of assorted therapeutic agents to targeted intracellular sites in a controlled release manner. Nanomedicine and nanoparticulate drug delivery systems are rapidly developing as they play crucial roles in the development of therapeutic strategies for various types of cancer and malignancy. Nevertheless, high costs, associated toxicity and production of complexities are some of the critical barriers for their applications. Green nanomedicines have continually been improved as one of the viable approaches towards tumor drug delivery, thus making a notable impact on which considerably affect cancer treatment. In this regard, the utilization of natural and renewable feedstocks as a starting point for the fabrication of nanosystems can considerably contribute to the development of green nanomedicines. Nanostructures and biopolymers derived from natural and biorenewable resources such as proteins, lipids, lignin, hyaluronic acid, starch, cellulose, gum, pectin, alginate, and chitosan play vital roles in the development of cancer nanotherapy, imaging and management. This review uncovers recent investigations on diverse nanoarchitectures fabricated from natural and renewable feedstocks for the controlled/sustained and targeted drug/gene delivery systems against cancers including an outlook on some of the scientific challenges and opportunities in this field. Various important natural biopolymers and nanomaterials for cancer nanotherapy are covered and the scientific challenges and opportunities in this field are reviewed.

Carbon-based nanomaterials for targeted cancer nanotherapy: recent trends and future prospects.

Carbon-based nanomaterials are becoming attractive materials due to their unique structural dimensions and promising mechanical, electrical, thermal, optical and chemical characteristics. Carbon nanotubes, graphene, graphene oxide, carbon and graphene quantum dots have numerous applications in diverse areas, including biosensing, drug/gene delivery, tissue engineering, imaging, regenerative medicine, diagnosis, and cancer therapy. Cancer remains one of the major health problems all over the world, and several therapeutic approaches are focussed on designing targeted anticancer drug delivery nanosystems by applying benign and less hazardous resources with high biocompatibility, ease of functionalization, remarkable targeted therapy issues, and low adverse effects. This review highlights the recent development on these carbon based-nanomaterials in the field of targeted cancer therapy and discusses their possible and promising diagnostic and therapeutic applications for the treatment of cancers.

Laser Ablation-Assisted Synthesis of Poly (Vinylidene Fluoride)/Au Nanocomposites: Crystalline Phase and Micromechanical Finite Element Analysis.

In this research, piezoelectric polymer nanocomposite films were produced through solution mixing of laser-synthesized Au nanoparticles in poly (vinylidene fluoride) (PVDF) matrix. Synthetization of Au nanoparticles was carried out by laser ablation in N-methyle-2-pyrrolidene (NMP), and then it was added to PVDF: NMP solution with three different concentrations. Fourier transformed infrared spectroscopy (FTIR) and X-ray diffraction (XRD) were carried out in order to study the crystalline structure of the nanocomposite films. Results revealed that a remakable change in crystalline polymorph of PVDF has occurred by embedding Au nanoparticles into the polymer matrix. The polar phase fraction was greatly improved by increasing the loading content of Au nanoparticle. Thermogravimetric analysis (TGA) showed that the nanocomposite films are more resistant to high temperature and thermal degradation. An increment in dielectric constant was noticed by increasing the concentration of Au nanoparticles through capacitance, inductance, and resistance (LCR) measurement. Moreover, the mechanical properties of nanocomposites were numerically anticipated by a finite element based micromechanical model. The results reveal an enhancement in both tensile and shear moduli.

Facile synthesis of graphitic carbon nitride/chitosan/Au nanocomposite: A catalyst for electrochemical hydrogen evolution.

This paper reports a novel nanocomposite catalyst comprised of graphitic carbon nitride (g-C3N4), chitosan and gold (Au) nanoparticles, which has been prepared through a facile, clean and low cost method. Graphitic carbon nitride has been fabricated by pyrolysis of urea. Laser ablation in liquid (LAL) was employed in the green synthesis of Au NPs. The g-C3N4/chitosan/Au nanocomposite (denoted as CN/CS/Au) were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDS), scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET) analyses. Chitosan biopolymer and a small amount of Au NPs were added to g-C3N4 to modify and improve the catalytic activity of g-C3N4. The activity of the hydrogen evolution reaction (HER) has been investigated using CN/CS/Au nanocomposite coated on a stainless steel mesh by electrochemical method. The amounts of hydrogen stored were calculated from cyclic voltammetry (CV) results. The results confirmed that chitosan and Au NPs were effective on the HER behavior of g-C3N4 and the nanocomposite had a good HER activity and stability.

Modification of Chitosan Membranes via Methane Ion Beam.

Chitosan has been used for biomedical applications in recent years, primarily because of its biocompatibility. A chitosan membrane with a 30 µm thickness was prepared and investigated for its surface modification using methane ions. Methane ions were implanted into the chitosan membrane using a Kaufman ion source; bombardment was accomplished using three accelerating voltages of ion beams-30, 55, and 80 keV. The influence of the ion bombardment on morphology, crystallinity, and hydrophilicity was investigated. Attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy analysis showed that a triplet bond appeared after the implantation of methane ions (acceleration voltage: 80 keV), culminating in the creation of a more amorphous membrane structure. The analyses of atomic force microscopy (AFM) images showed that, with the increase in bombardment energy, the roughness of the surface changed. These results revealed that ion bombardment improved the hydrophilicity of the membranes and the water fluxes of chitosan membranes altered after methane ion bombardment.

Upgraded Valorization of Biowaste: Laser-Assisted Synthesis of Pd/Calcium Lignosulfonate Nanocomposite for Hydrogen Storage and Environmental Remediation.

Laser ablation in liquid (LAL), one of the promising pathways to produce nanoparticles, is used herein for the modification of the abundant biowaste, calcium lignosulfonate (CLS), adorning it with palladium nanoparticles (Pd NPs). The ensuing Pd/CLS nanocomposite, fabricated via a simple stirring method, is deployed for hydrogen storage and environmental cleanup studies; a hydrogen storage capacity of about 5.8 C g-1 confirmed that Pd NPs serve as active sites for the adsorption of hydrogen. Additionally, the novel, sustainable, and reusable nanocomposite also exhibits superior catalytic activity toward the reduction of hexavalent chromium [Cr(VI)], 4-nitrophenol (4-NP), and methylene blue (MB) in an aqueous solution in a short time; the synthesized nanocatalyst could be reused for at least eight successive runs.

Laser-assisted preparation of Pd nanoparticles on carbon cloth for the degradation of environmental pollutants in aqueous medium.

Laser ablation in liquid (LAL), one of the attractive methods for fabrication of nanoparticles, was used for the modification of carbon cloth (CC) by deposition of palladium nanoparticles (Pd NPs); a simple stirring method was deployed to deposit Pd NPs on the CC surface. Characterization techniques viz X-ray diffraction (XRD), Fourier transform infrared (FT-IR), scanning electron microscope (SEM), energy-dispersive X-ray spectrometry (EDS) and inductively coupled plasma atomic emission spectroscopy (ICP-AES) were applied to study the surface of the ensuing samples which confirmed that LAL technique managed to fabricate and deposit the Pd NPs on the surface of CC. In addition, the catalytic prowess of the carbon cloth-Pd NPs (CC/Pd NPs) was investigated in the NaBH4- or HCOOH-assisted reduction of assorted environmental pollutants in aqueous medium namely hexavalent chromium [Cr(VI)], 4-nitrophenol (4-NP), congo red (CR) and methylene blue (MB). The CC/Pd NPs system has advantages such as high stability/sustainability, high catalytic performance and easy reusability.

Improving Wettability: Deposition of TiO2 Nanoparticles on the O2 Plasma Activated Polypropylene Membrane.

Radio frequency plasma is one of the means to modify the polymer surface namely in the activation of polypropylene membranes (PPM) with O2 plasma. Activated membranes were deposited with TiO2 nanoparticles by the dip coating method and the bare sample and modified sample (PPM5-TiO2) were irradiated by UV lamps for 20-120 min. Characterization techniques such as X-ray diffraction (XRD), Attenuated total reflection technique- Fourier transform infrared spectroscopy (ATR-FTIR), Thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), Scanning electron microscope (SEM) and water contact angle (WCA) measurements were applied to study the alteration of ensuing membrane surface properties which shows the nanoparticles on the sample surface including the presence of Ti on PPM. The WCA decreased from 135° (PPM) to 90° (PPM5-TiO2) and after UV irradiation, the WCA of PPM5-TiO2 diminished from 90° to 40°.